Encoding molecular-wire formation within nanoscale sockets (2007)
Abstract
Wire straits: Three-component molecular wires were constructed in situ by first assembling a monolayer of a bifunctional arene on the electrode surfaces, such that only one end of the molecule (thiol) reacts with the electrode. Then, a second molecule was used to chemically bridge the gap between the termini of the films. Coordination chemistry in this context provides a versatile method to reversibly form molecular-scale wires (see picture). EDTA=ethylenediaminetetraacetate.
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